In User fields, add field of type: List Text with checkboxes radio button as widget
Use the Filed Permissions module so only admins can see this user field.
Download Rules and enable Rules UI
###Create a New Rule
Create a New Rule
React on: After Updating an Existing User Account
Add Condition: Data Comparison >> account-unchanged:status >> Operator: Equals DATA Value: Blocked
Add Action >> Send Mail >> Body: [user:name] was blocked because [user:field-example]