Try with print render($node_author->field_custom);
Or you can try as well:
insert at the top of you node.tpl.php
<?php
global $user;
$node_author = user_load($user->uid);
$yourvariable = $node_author->field_custom;
?>
Where you want print the field insert:
<?php print $yourvariable['und'][0]['value'];?>