Guess what, if for some reason (such as this one), you can't get it to work with the prior answer, then you may want to try an approach which is like "the other way around". Read on for more details on that approach ...
Step 1
Start with creating an extremely basic Rules Component, which includes whatever Rules Conditions you might need (if any), and with a Rules Action to flag (using the Flag module) a user, whereas you specify the user to be flagged as a parameter for that Rules Component. FYI: this is really like a getting started with Rules ...
Step 2
Create a view of your existing members of an OG group that you want to be flagged. Maybe you already have such view that you can use. Then transform that view into a view that uses Views Bulk Operations, and use the technique documented in "How to use Rules to create a custom bulk operation for a VBO view?".
In doing so, you'll then be able to use Rules Components (using the Rules module), in which you can then include the required logic to flag a single user with your flag. If you wonder how to create such Rule that would fit your VBO view (ie that you can use in it), then use this link ...
Attention
Even though one may think "Hm, is it really that easy?", it happens that after you created a Rules Component and try to use it in a VBO view, that Rules Component cannot be selected as an operation to be enabled in your VBO view. If that happens, and you wonder what it would take to try to make it show up anyway (in the VBO view), then use this link ...