In Drupal 7, I can do this in a custom field template to print the alt tag of an image:
<?php print $item['#item']['alt']; ?>
And though "item" seems to be a variable in Twig / drupal 8 fields, I can't seem to do the same thing. I've tried these:
{{ item.alt }}
{{ item.item.alt }}
These don't work but I don't get any errors either. Looking at the API does not give me much insight. I saw this gist but again, no alt tag rendered separately. My image is rendering the alt tag as i can see it in the code though.