I'm trying to place "Add new item" button before the unlimited values field. Also two buttons un top and below field will work. In custom module added new button but it brakes AJAX call for both buttons. This is needed for Field collection field but I doubt it matters. This is how I've tried to build second button:
$form['field_fieldname']['add_more2'] = array(
'#type' => 'submit',
'#name' => 'field_fieldname_add_more',
'#value' => t('Add another item'),
'#submit' => array('field_add_more_submit'),
'#ajax' => array('callback'=>'field_add_more_js','wrapper'=>'field-fieldname-add-more-wrapper','effect'=>'fade',),
'#limit_validation_errors' => array(array('field_fieldname','und')),
'#attributes' => array('class'=>array('field-add-more-submit'))
);